Generation of nitrile N-selenides, RC≡NSe, as neutrals and radical cations in the gas phase

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4039(97)10228-3

Title:	Generation of nitrile N-selenides, RC≡NSe, as neutrals and radical cations in the gas phase
Authors:	Gerbaux, P. Flammang, R. Mørkved, E.H. Wong, M.W. Wentrup, C.
Issue Date:	12-Feb-1998
Citation:	Gerbaux, P., Flammang, R., Mørkved, E.H., Wong, M.W., Wentrup, C. (1998-02-12). Generation of nitrile N-selenides, RC≡NSe, as neutrals and radical cations in the gas phase. Tetrahedron Letters 39 (7) : 533-536. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(97)10228-3
Abstract:	Cyanogen N-selenide radical cation, NCCNSe.+, is prepared by dissociative ionization of 3,4-dicyano-1,2,5-selenadiazole [1]. It reacts readily with nitriles in the gas phase to produce nitrile N-selenide ions, RCNSe.+. The stability of the corresponding neutral dipoles is confirmed by neutralization-reionization mass spectrometric experiments.
Source Title:	Tetrahedron Letters
URI:	http://scholarbank.nus.edu.sg/handle/10635/93885
ISSN:	00404039
DOI:	10.1016/S0040-4039(97)10228-3
Appears in Collections:	Staff Publications

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