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|Title:||General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates|
|Citation:||Wang, P., Shannigrahi, S., Yakovlev, N.L., Hor, T.S.A. (2012-11-19). General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates. Inorganic Chemistry 51 (22) : 12059-12061. ScholarBank@NUS Repository. https://doi.org/10.1021/ic301527b|
|Abstract:||A new family of Co/rare-earth intermetallic cubane aggregates [Co 3Ln(hmp) 4(OAc) 5H 2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co 3Ln] core. Magnetic studies showed that the Dy, Er, Tm, Yb, and Y complexes are ferromagnetic. The Dy complex exhibits the largest magnetocaloric effect (-ΔS m = 12.58 J kg -1 K -1), which can be attributed to the large magnetic density of Dy III. © 2012 American Chemical Society.|
|Source Title:||Inorganic Chemistry|
|Appears in Collections:||Staff Publications|
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