Please use this identifier to cite or link to this item:
|Title:||Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)|
|Authors:||Bai, S.-Q. |
|Citation:||Bai, S.-Q., Kwang, J.Y., Koh, L.L., Young, D.J., Hor, T.S.A. (2010). Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i). Dalton Transactions 39 (10) : 2631-2636. ScholarBank@NUS Repository. https://doi.org/10.1039/b918223c|
|Abstract:||Two 3-D and one 2-D metal-organic frameworks [Cu8I 8(L1)4]n (1), [Cu8I 8(L2)4]n (2) and [Cu4I 4(L3)2]n (3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2, 3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole (L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(i) oligomer and Cu4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence. © The Royal Society of Chemistry 2010.|
|Source Title:||Dalton Transactions|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on May 20, 2018
WEB OF SCIENCETM
checked on Apr 24, 2018
checked on Mar 12, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.