Please use this identifier to cite or link to this item: https://doi.org/10.1039/b918223c
Title: Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)
Authors: Bai, S.-Q. 
Kwang, J.Y.
Koh, L.L. 
Young, D.J.
Hor, T.S.A. 
Issue Date: 2010
Citation: Bai, S.-Q., Kwang, J.Y., Koh, L.L., Young, D.J., Hor, T.S.A. (2010). Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i). Dalton Transactions 39 (10) : 2631-2636. ScholarBank@NUS Repository. https://doi.org/10.1039/b918223c
Abstract: Two 3-D and one 2-D metal-organic frameworks [Cu8I 8(L1)4]n (1), [Cu8I 8(L2)4]n (2) and [Cu4I 4(L3)2]n (3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2, 3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole (L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(i) oligomer and Cu4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence. © The Royal Society of Chemistry 2010.
Source Title: Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/93869
ISSN: 14779226
DOI: 10.1039/b918223c
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