Please use this identifier to cite or link to this item:
|Title:||From molecular complexes to zwitterions and final products. Reactions between C3O2 and amines|
Pierre Aycard, J.
|Citation:||Sessouma, B., Couturier-Tamburelli, I., Monnier, M., Wong, M.W., Wentrup, C., Pierre Aycard, J. (2002-05-09). From molecular complexes to zwitterions and final products. Reactions between C3O2 and amines. Journal of Physical Chemistry A 106 (18) : 4489-4497. ScholarBank@NUS Repository. https://doi.org/10.1021/jp0134190|
|Abstract:||The formation of molecular complexes (prereactive intermediates) between C3O2 and amines (ammonia, dimethylamine, trimethylamine, and 4-(dimethylamino)pyridine) as well as the subsequent transformation of the complexes into C3O2-amine zwitterions in cryogenic matrixes (ca. 40 K) has been observed. In the case of dimethylamine, the formation of tetramethylmalonamide has also been documented. Calculations using density functional theory (B3LYP/6-31G(2d, p)) are used to assign all above species and are in excellent agreement with the IR spectra.|
|Source Title:||Journal of Physical Chemistry A|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 20, 2019
WEB OF SCIENCETM
checked on Jan 1, 2019
checked on Jan 11, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.