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Please use this identifier to cite or link to this item: https://doi.org/10.1016/0040-4039(95)01791-F
DC FieldValue
dc.titleFormation of bifluorenylidene from 9-mercaptofluorene via a sulfide autoxidation-anionic autoxidation-elimination sequence
dc.contributor.authorLai, Y.-H.
dc.contributor.authorLee, S.-M.
dc.date.accessioned2014-10-16T08:29:02Z
dc.date.available2014-10-16T08:29:02Z
dc.date.issued1995-11-20
dc.identifier.citationLai, Y.-H., Lee, S.-M. (1995-11-20). Formation of bifluorenylidene from 9-mercaptofluorene via a sulfide autoxidation-anionic autoxidation-elimination sequence. Tetrahedron Letters 36 (47) : 8679-8680. ScholarBank@NUS Repository. https://doi.org/10.1016/0040-4039(95)01791-F
dc.identifier.issn00404039
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93839
dc.description.abstractBifluorenylidene 1 was formed quantitatively when 9-mercaptofluorene 3 was treated with base and exposed to air. The initial step was established to be an intermolecular autoxidation of sulphide ion to form the disulphide 6. An intramolecular autoxidation of the dianion 8 derived from 6 was expected to afford a 1,2-dithietane derivative 9 which eliminated sulphur to give bifluorenylidene 1. © 1995 Elsevier Science Ltd.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/0040-4039(95)01791-F
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/0040-4039(95)01791-F
dc.description.sourcetitleTetrahedron Letters
dc.description.volume36
dc.description.issue47
dc.description.page8679-8680
dc.description.codenTELEA
dc.identifier.isiutA1995TF21000041
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