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|Title:||Formation of a novel delocalised diphosphazene upon complexation. The preparation and X-ray structure of Pd2Cl4[(CF 3)2P=N=PPh3]2|
|Authors:||Ang, H.G. |
|Citation:||Ang, H.G., Cai, Y.M., Kwik, W.L., Rheingold, A.L. (1990). Formation of a novel delocalised diphosphazene upon complexation. The preparation and X-ray structure of Pd2Cl4[(CF 3)2P=N=PPh3]2. Journal of the Chemical Society, Chemical Communications (22) : 1580-1581. ScholarBank@NUS Repository. https://doi.org/10.1039/C39900001580|
|Abstract:||Reaction of (CF3)2P-N=PPh3(L) with PdCl2 in dichloromethane gives Pd2Cl4[(CF 3)2P=N=PPh3]2, 1 in which L has been shown from spectroscopic and X-ray crystallographic analyses to assume an uncharged non-linear electronic structure [Ph3P=N=P(CF 3)2], where the P-N and N-P bonds are equidistant and the PNP segment is highly delocalised.|
|Source Title:||Journal of the Chemical Society, Chemical Communications|
|Appears in Collections:||Staff Publications|
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