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https://scholarbank.nus.edu.sg/handle/10635/93833
| Title: | Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry | Authors: | Leong, W.K. Liu, Y. |
Issue Date: | 15-Feb-1999 | Citation: | Leong, W.K.,Liu, Y. (1999-02-15). Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry. Organometallics 18 (4) : 800-802. ScholarBank@NUS Repository. | Abstract: | Bromination of the substituted triosmium dusters Os3(CO)10(EPh3)2 (E = P, As) yielded the cluster cations [Os3(CO)10(EPh3)2(μ-Br)] +, which crystallized as the [Os(CO)3Br3]- salts. The osmate anions were the result of nucleophilic attack of Br- on the cluster cations. | Source Title: | Organometallics | URI: | http://scholarbank.nus.edu.sg/handle/10635/93833 | ISSN: | 02767333 |
| Appears in Collections: | Staff Publications |
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