Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93833
Title: Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry
Authors: Leong, W.K. 
Liu, Y.
Issue Date: 15-Feb-1999
Source: Leong, W.K.,Liu, Y. (1999-02-15). Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry. Organometallics 18 (4) : 800-802. ScholarBank@NUS Repository.
Abstract: Bromination of the substituted triosmium dusters Os3(CO)10(EPh3)2 (E = P, As) yielded the cluster cations [Os3(CO)10(EPh3)2(μ-Br)] +, which crystallized as the [Os(CO)3Br3]- salts. The osmate anions were the result of nucleophilic attack of Br- on the cluster cations.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/93833
ISSN: 02767333
Appears in Collections:Staff Publications

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