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|Title:||Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry|
|Authors:||Leong, W.K. |
|Source:||Leong, W.K.,Liu, Y. (1999-02-15). Formation of [Os3(CO)10(EPh3)2(μ-Br)] + (E = P, As) by bromination: First direct evidence for the bromonium mechanism in cluster chemistry. Organometallics 18 (4) : 800-802. ScholarBank@NUS Repository.|
|Abstract:||Bromination of the substituted triosmium dusters Os3(CO)10(EPh3)2 (E = P, As) yielded the cluster cations [Os3(CO)10(EPh3)2(μ-Br)] +, which crystallized as the [Os(CO)3Br3]- salts. The osmate anions were the result of nucleophilic attack of Br- on the cluster cations.|
|Appears in Collections:||Staff Publications|
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