Please use this identifier to cite or link to this item: https://doi.org/10.1002/asia.201300838
Title: Facile self-assembly of intermetallic [Ni2Gd2] cubane aggregate for magnetic refrigeration
Authors: Wang, P.
Shannigrahi, S.
Yakovlev, N.L.
Hor, T.S.A. 
Keywords: heterometallic complexes
intermetallic
magnetic properties
magnetocaloric effect
metal aggregates
Issue Date: Dec-2013
Citation: Wang, P., Shannigrahi, S., Yakovlev, N.L., Hor, T.S.A. (2013-12). Facile self-assembly of intermetallic [Ni2Gd2] cubane aggregate for magnetic refrigeration. Chemistry - An Asian Journal 8 (12) : 2943-2946. ScholarBank@NUS Repository. https://doi.org/10.1002/asia.201300838
Abstract: Cubane Cooler: An intermetallic cubane aggregate shows a pronounced cryogenic magnetocaloric effect (MCE). A mixed-metal [Ni2Gd 2] cubane was assembled by the use of 2-(hydroxymethyl)pyridine (hmpH) as a spacer in a simple one-pot reaction. Its MCE measurement gives 34.4 J kg-1 K-1 at 4.5 K, suggesting that, apart from the commonly used large-nuclearity metal aggregates, smaller metal cubanes can also exhibit a large MCE. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Chemistry - An Asian Journal
URI: http://scholarbank.nus.edu.sg/handle/10635/93798
ISSN: 18614728
DOI: 10.1002/asia.201300838
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