Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93797
Title: Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide
Authors: Chin, C.H.
Hor, T.S.A. 
Keywords: Carbon monoxide
Carbonyl sulfide
Desulfurization
Platinum
Reductive carbonylation
Sulfide
Issue Date: 1996
Source: Chin, C.H.,Hor, T.S.A. (1996). Facile reductive excision of sulfur from a {Pt2S2} core in [Pt2(PPh3)4(μ-S)2] to a {Pt2S} triangle by carbon monoxide. Journal of Organometallic Chemistry 509 (1) : 101-104. ScholarBank@NUS Repository.
Abstract: A synthetic path is established in which [Pt2(CO)x(PPh3)4-x(μ-S)] (x = 0-2) can be prepared from [Pt2(PPh3)4(μ-S)2] under CO at low pressure whereby reductive desulfurization of a {Pt2 11S2} core gives way to a Pt-Pt bonded {Pt2 1S} triangle with extrusion of COS gas.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/93797
ISSN: 0022328X
Appears in Collections:Staff Publications

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