Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93732
Title: Enantiodivergent and γ-selective asymmetric allylic amination
Authors: Wang, J.
Chen, J.
Kee, C.W.
Tan, C.-H. 
Keywords: allylic compounds
asymmetric synthesis
homogeneous catalysis
organocatalysis
synthetic methods
Issue Date: 5-Mar-2012
Source: Wang, J., Chen, J., Kee, C.W., Tan, C.-H. (2012-03-05). Enantiodivergent and γ-selective asymmetric allylic amination. Angewandte Chemie - International Edition 51 (10) : 2382-2386. ScholarBank@NUS Repository.
Abstract: Double agent: The title reaction using the guanidine catalyst 1 can deliver both enantiomers of the product with excellent enantioselectivity by judicious choice of the double bond geometry of the the β,γ-unsaturated carbonyl compound. Computational studies reveal the possible origin of the inversed enantioselectivity, and the potential for enantiodivergent synthesis chiral amine-containing substrates is attractive. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/93732
ISSN: 14337851
Appears in Collections:Staff Publications

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