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|Title:||Electronic structure of arsinous azides|
|Authors:||Ang, H.G. |
|Source:||Ang, H.G.,Lee, Y.W.,Novak, I.,Potts, A.W. (1994). Electronic structure of arsinous azides. Journal of Physical Chemistry 98 (48) : 12526-12529. ScholarBank@NUS Repository.|
|Abstract:||He and I and He II photoelectron spectra (UPS) of (CF3)2AsN3 and CF3As(N3)2 have been measured and assigned on the basis of HeI/HeII intensity variations, band shapes, comparison with UPS of HN3 amd (CF3)xAsH3-x (x = 1, 2), and semiempirical MO calculations. The results for CF3As(N3)2 represent the first UPS study of a covalent diazide. They indicate that in both azides, the As 4p orbital has lost its lone pair character, being heavily mixed with the azide group orbitals. © 1994 American Chemical Society.|
|Source Title:||Journal of Physical Chemistry|
|Appears in Collections:||Staff Publications|
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