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Title: Electronic structure of arsinous azides
Authors: Ang, H.G. 
Lee, Y.W.
Novak, I. 
Potts, A.W.
Issue Date: 1994
Source: Ang, H.G.,Lee, Y.W.,Novak, I.,Potts, A.W. (1994). Electronic structure of arsinous azides. Journal of Physical Chemistry 98 (48) : 12526-12529. ScholarBank@NUS Repository.
Abstract: He and I and He II photoelectron spectra (UPS) of (CF3)2AsN3 and CF3As(N3)2 have been measured and assigned on the basis of HeI/HeII intensity variations, band shapes, comparison with UPS of HN3 amd (CF3)xAsH3-x (x = 1, 2), and semiempirical MO calculations. The results for CF3As(N3)2 represent the first UPS study of a covalent diazide. They indicate that in both azides, the As 4p orbital has lost its lone pair character, being heavily mixed with the azide group orbitals. © 1994 American Chemical Society.
Source Title: Journal of Physical Chemistry
ISSN: 00223654
Appears in Collections:Staff Publications

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