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|Title:||Diverse cyclization catalyzed by in(OTf)3 for the convergent assembly of substituted tetrahydrofurans and tetrahydropyrans|
|Authors:||Loh, T.-P. |
|Citation:||Loh, T.-P., Hu, Q.-Y., Tan, K.-T., Cheng, H.-S. (2001-08-23). Diverse cyclization catalyzed by in(OTf)3 for the convergent assembly of substituted tetrahydrofurans and tetrahydropyrans. Organic Letters 3 (17) : 2669-2672. ScholarBank@NUS Repository. https://doi.org/10.1021/ol016228o|
|Abstract:||(Equation presented) A novel In(OTf)3-catalyzed (3,5) oxonium-ene type cyclization for the facile construction of various multisubstituted tetrahydrofurans and tetrahydropyrans was successfully developed. Further mechanistic investigations unveiled an In(OTf)3-catalyzed skeletal reorganization of the tetrahydrofuran to its thermodynamic isomer under thermal conditions.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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