Please use this identifier to cite or link to this item: https://doi.org/10.1002/aoc.687
Title: Di- and tri-organotin(IV) derivatives of (Z)-3-(4-nitrophenyl)-2-phenyl-2- propenoic acid: Spectroscopic characterization and biocidal studies. Crystal structure analysis of tetrameric tri-n-butyltin(IV) (Z)-3-(4-nitrophenyl)-2- phenyl-2-propenoate
Authors: Sadiq-Ur-Rehman
Ali, S.
Badshah, A.
Malik, A.
Ahmed, E.
Jin, G.-X.
Tiekink, E.R.T. 
Keywords: Biocidal activity
Carboxylates
Organotin(IV)
Tetrameric structure
X-ray crystal structure
Issue Date: Aug-2004
Citation: Sadiq-Ur-Rehman, Ali, S., Badshah, A., Malik, A., Ahmed, E., Jin, G.-X., Tiekink, E.R.T. (2004-08). Di- and tri-organotin(IV) derivatives of (Z)-3-(4-nitrophenyl)-2-phenyl-2- propenoic acid: Spectroscopic characterization and biocidal studies. Crystal structure analysis of tetrameric tri-n-butyltin(IV) (Z)-3-(4-nitrophenyl)-2- phenyl-2-propenoate. Applied Organometallic Chemistry 18 (8) : 401-408. ScholarBank@NUS Repository. https://doi.org/10.1002/aoc.687
Abstract: Seven new organotin(IV) compounds containing the carboxylate ligand (Z)-3-(4-nitrophenyl)-2-phenyl-2-propenoate (L) have been synthesized with formulations of R2SnL2 (R = Me, Et, n-Bu, n-Oct) and R3SnL, (R = Me, n-Bu, Ph). All compounds have been studied in solution by multinuclear (1H, 13C, 119Sn) magnetic resonance spectroscopy. The solid-state structures have been investigated by means of FT-IR spectroscopy and the molecular structure of one example, namely n-Bu3SnL, has been determined by X-ray crystallography. The novel structure of n-Bu3SnL is tetrameric owing to the presence of bidentate bridging carboxylate ligands. The solution studies show collapse of the intermolecular interactions observed in the solid state to yield monomeric species. Some of the new compounds were found to display significant biocidal activities. Copyright © 2004 John Wiley & Sons, Ltd.
Source Title: Applied Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/93577
ISSN: 02682605
DOI: 10.1002/aoc.687
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