Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201310136
Title: Desymmetrization of diolefinic diols by enantioselective amino-thiocarbamate-catalyzed bromoetherification: Synthesis of chiral spirocycles
Authors: Tay, D.W.
Leung, G.Y.C.
Yeung, Y.-Y. 
Keywords: asymmetric catalysis
chemoselectivity
cyclization
furans
Lewis base
Issue Date: 12-May-2014
Citation: Tay, D.W., Leung, G.Y.C., Yeung, Y.-Y. (2014-05-12). Desymmetrization of diolefinic diols by enantioselective amino-thiocarbamate-catalyzed bromoetherification: Synthesis of chiral spirocycles. Angewandte Chemie - International Edition 53 (20) : 5161-5164. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201310136
Abstract: A facile, efficient, and highly diastereo- and enantioselective bromoetherification of diolefinic diols has been developed using an amino-thiocarbamate catalyst. Further manipulations of the bromoether products enabled entry into a new class of spirocycles which are distinctively lacking in the literature. Seeing double: A facile, efficient, and highly diastereo- and enantioselective bromoetherification of diolefinic diols has been developed using an amino-thio-carbamate catalyst. Further manipulations of the bromoether products enabled entry into a new class of spirocycles, having three stereogenic quaternary carbon centers, which are distinctively lacking in the literature. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/93534
ISSN: 15213773
DOI: 10.1002/anie.201310136
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