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|Title:||Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors|
|Citation:||Ye, Q., Chang, J., Huang, K.-W., Shi, X., Wu, J., Chi, C. (2013-03-15). Cyanated diazatetracene diimides with ultrahigh electron affinity for n-channel field effect transistors. Organic Letters 15 (6) : 1194-1197. ScholarBank@NUS Repository. https://doi.org/10.1021/ol400082c|
|Abstract:||Several diazatetracene diimides with high electron affinity (up to 4.66 eV!) were prepared and well characterized. The LUMO energy level of these electron-deficient molecules was found to be closely related to their material stability. Compound 7 with ultrahigh electron affinity suffered from reduction and hydrolysis in the presence of silica gel or water. The stable compounds 3 and 6 showed n-channel FET behavior with an average electron mobility of 0.002 and 0.005 cm2 V-1 s-1, respectively, using a solution processing method. © 2013 American Chemical Society.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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