Please use this identifier to cite or link to this item: https://doi.org/10.1002/1521-3773(20010903)40:173.0.CO;2-#
Title: C-S bond cleavage and C-C coupling in cyclopentadienylchromium complexes to give the first dithiooxamide-bridged and doubly dithiocarbamate-bridged double cubanes: [Cp6Cr8S8{(C(S)NEt2) 2}] and [Cp6Cr8S8(S2CNEt2) 2]
Authors: Goh, L.Y. 
Weng, Z. 
Leong, W.K. 
Leung, P.H. 
Keywords: Chromium
Cluster compounds
Cubanes
S ligands
Issue Date: 3-Sep-2001
Source: Goh, L.Y.,Weng, Z.,Leong, W.K.,Leung, P.H. (2001-09-03). C-S bond cleavage and C-C coupling in cyclopentadienylchromium complexes to give the first dithiooxamide-bridged and doubly dithiocarbamate-bridged double cubanes: [Cp6Cr8S8{(C(S)NEt2) 2}] and [Cp6Cr8S8(S2CNEt2) 2]. Angewandte Chemie - International Edition 40 (17) : 3236-3239. ScholarBank@NUS Repository. https://doi.org/10.1002/1521-3773(20010903)40:173.0.CO;2-#
Abstract: Thermolysis of the Dithiocarbamate complex 1 led to the formation of the thiocarbenoid complex 2 and two double cubanes: 3, which has an intercubane Cr-Cr bond and a dithiooxamide ligand in the μ-η2,η4 bonding mode, and 4, which contains two dithiocarbamate ligands in the μ-η1,η2 bonding mode.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/93509
ISSN: 14337851
DOI: 10.1002/1521-3773(20010903)40:173.0.CO;2-#
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