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https://doi.org/10.1002/1521-3773(20010903)40:173.0.CO;2-#
Title: | C-S bond cleavage and C-C coupling in cyclopentadienylchromium complexes to give the first dithiooxamide-bridged and doubly dithiocarbamate-bridged double cubanes: [Cp6Cr8S8{(C(S)NEt2) 2}] and [Cp6Cr8S8(S2CNEt2) 2] | Authors: | Goh, L.Y. Weng, Z. Leong, W.K. Leung, P.H. |
Keywords: | Chromium Cluster compounds Cubanes S ligands |
Issue Date: | 3-Sep-2001 | Citation: | Goh, L.Y.,Weng, Z.,Leong, W.K.,Leung, P.H. (2001-09-03). C-S bond cleavage and C-C coupling in cyclopentadienylchromium complexes to give the first dithiooxamide-bridged and doubly dithiocarbamate-bridged double cubanes: [Cp6Cr8S8{(C(S)NEt2) 2}] and [Cp6Cr8S8(S2CNEt2) 2]. Angewandte Chemie - International Edition 40 (17) : 3236-3239. ScholarBank@NUS Repository. https://doi.org/10.1002/1521-3773(20010903)40:173.0.CO;2-# | Abstract: | Thermolysis of the Dithiocarbamate complex 1 led to the formation of the thiocarbenoid complex 2 and two double cubanes: 3, which has an intercubane Cr-Cr bond and a dithiooxamide ligand in the μ-η2,η4 bonding mode, and 4, which contains two dithiocarbamate ligands in the μ-η1,η2 bonding mode. | Source Title: | Angewandte Chemie - International Edition | URI: | http://scholarbank.nus.edu.sg/handle/10635/93509 | ISSN: | 14337851 | DOI: | 10.1002/1521-3773(20010903)40:173.0.CO;2-# |
Appears in Collections: | Staff Publications |
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