Please use this identifier to cite or link to this item: https://doi.org/10.1039/c0dt00273a
Title: Crystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]·{[Na3(OH2) 8]3[NaPd3(C6H4O 7)3]2}·(H2O) stabilised by intermetallic aggregation with sodium and heavy hydration
Authors: Gunari, P. 
Krishnasamy, S.
Bai, S.-Q. 
Hor, T.S.A. 
Issue Date: 28-Oct-2010
Citation: Gunari, P., Krishnasamy, S., Bai, S.-Q., Hor, T.S.A. (2010-10-28). Crystallographic identification of an unusual homoleptic palladium citrate [Na(OH2)6]·{[Na3(OH2) 8]3[NaPd3(C6H4O 7)3]2}·(H2O) stabilised by intermetallic aggregation with sodium and heavy hydration. Dalton Transactions 39 (40) : 9462-9464. ScholarBank@NUS Repository. https://doi.org/10.1039/c0dt00273a
Abstract: A rare precious metal binary citrate represented by palladium in the form of a water-rich Na-Pd intermetallic aggregate has been isolated and crystallographically characterised. It shows a penta-anionic [NaPd 3(citrate)3]5- core balanced by [Na 3]3+ and Na+ hydrates in a 3-D coordination network stabilised exclusively by citrate bridges and fortified by extensive H-bonding. © 2010 The Royal Society of Chemistry.
Source Title: Dalton Transactions
URI: http://scholarbank.nus.edu.sg/handle/10635/93506
ISSN: 14779226
DOI: 10.1039/c0dt00273a
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