Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.tetlet.2004.04.064
Title: Convenient synthesis of mono(6A-N-allylamino-6 A-deoxy)permethylated β-cyclodextrin: A promising chiral selector for an HPLC chiral stationary phase
Authors: Lai, X.-H.
Ng, S.-C. 
Keywords: Chiral stationary phase
Cyclodextrin
Permethylation
Issue Date: 31-May-2004
Source: Lai, X.-H., Ng, S.-C. (2004-05-31). Convenient synthesis of mono(6A-N-allylamino-6 A-deoxy)permethylated β-cyclodextrin: A promising chiral selector for an HPLC chiral stationary phase. Tetrahedron Letters 45 (23) : 4469-4472. ScholarBank@NUS Repository. https://doi.org/10.1016/j.tetlet.2004.04.064
Abstract: Mono(6-(p-toluenesulfonyl))permethylated β-cyclodextrin, a versatile precursor for a wide variety of mono-functionalized permethyl β-cyclodextrins, has been generated successfully by the direct methylation of monotosylated cyclodextrin. This afforded a convenient synthesis of mono(6A-N-allylamino-6A-deoxy)permethylated β-cyclodextrin. Hydrosilylation of the chiral selector with (EtO) 3SiH and reaction of the resultant reactive siloxane with pristine silica gel afforded a facile entry into a structurally well-defined chiral HPLC stationary phase. © 2004 Elsevier Ltd. All rights reserved.
Source Title: Tetrahedron Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/93374
ISSN: 00404039
DOI: 10.1016/j.tetlet.2004.04.064
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

17
checked on Feb 14, 2018

WEB OF SCIENCETM
Citations

7
checked on Feb 14, 2018

Page view(s)

21
checked on Feb 11, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.