Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.cplett.2005.06.008
DC Field | Value | |
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dc.title | Coexistence of ketenimine species and tetra-σ adduct at acetyl cyanide/Si(1 0 0)-2 × 1 | |
dc.contributor.author | Huang, J.Y. | |
dc.contributor.author | Huang, H.G. | |
dc.contributor.author | Ning, Y.S. | |
dc.contributor.author | Liu, Q.P. | |
dc.contributor.author | Alshahateet, S.F. | |
dc.contributor.author | Sun, Y.M. | |
dc.contributor.author | Xu, G.Q. | |
dc.date.accessioned | 2014-10-16T08:23:01Z | |
dc.date.available | 2014-10-16T08:23:01Z | |
dc.date.issued | 2005-08-05 | |
dc.identifier.citation | Huang, J.Y., Huang, H.G., Ning, Y.S., Liu, Q.P., Alshahateet, S.F., Sun, Y.M., Xu, G.Q. (2005-08-05). Coexistence of ketenimine species and tetra-σ adduct at acetyl cyanide/Si(1 0 0)-2 × 1. Chemical Physics Letters 411 (1-3) : 75-80. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cplett.2005.06.008 | |
dc.identifier.issn | 00092614 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93323 | |
dc.description.abstract | The covalent binding of acetyl cyanide on Si(1 0 0)-2 × 1 has been investigated using high-resolution electron energy loss spectroscopy, X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations. The absence of the C=O and C≡N stretching modes in the EELS spectra for chemisorbed molecules indicates the direct interactions between carbonyl, cyano groups and the dangling bonds on Si(1 0 0)-2 × 1. The characteristic C=C=N asymmetric stretching mode at 2031 cm-1 and C=N stretching mode at 1667 cm-1 suggest the existence of both ketenimine species and tetra-σ adduct at the interface, further supported by XPS results and DFT calculations. © 2005 Elsevier B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.cplett.2005.06.008 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.cplett.2005.06.008 | |
dc.description.sourcetitle | Chemical Physics Letters | |
dc.description.volume | 411 | |
dc.description.issue | 1-3 | |
dc.description.page | 75-80 | |
dc.description.coden | CHPLB | |
dc.identifier.isiut | 000230980700015 | |
Appears in Collections: | Staff Publications |
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