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|Title:||Catalytic reductive coupling of 9-bromofluorene|
|Citation:||Sridevi, V.S., Leong, W.K., Zhu, Y. (2006-01-02). Catalytic reductive coupling of 9-bromofluorene. Organometallics 25 (1) : 283-288. ScholarBank@NUS Repository. https://doi.org/10.1021/om050850t|
|Abstract:||The reductive homocoupling of 9-bromofluorene is catalyzed by 0.1 mol % Ru3(CO)12 in refluxing xylene, with a TON in excess of 3000. A stoichiometric reaction affords the novel cluster Ru4(μ 3-OMe)-(μ3-OH)(μ-Br)2(CO)10, which is found to be even more catalytically active. Further reaction of this cluster with bromofluorene gives another novel cluster, Ru4(μ 4-O)(μ-Br)6(CO)8, which is inactive. © 2006 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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