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|Title:||Catalytic asymmetric bromoetherification and desymmetrization of olefinic 1,3-diols with C2-symmetric sulfides|
|Citation:||Ke, Z., Tan, C.K., Chen, F., Yeung, Y.-Y. (2014-04-16). Catalytic asymmetric bromoetherification and desymmetrization of olefinic 1,3-diols with C2-symmetric sulfides. Journal of the American Chemical Society 136 (15) : 5627-5630. ScholarBank@NUS Repository. https://doi.org/10.1021/ja5029155|
|Abstract:||An enantioselective and highly diastereoselective bromoetherification and desymmetrization of olefinic 1,3-diols has been developed using a C 2-symmetric cyclic sulfide catalyst. This methodology has been successfully applied to the synthesis of the key intermediate of an orally active antifungal drug posaconazole (Noxafil). © 2014 American Chemical Society.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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