Please use this identifier to cite or link to this item:
|Title:||Asymmetric synthesis of a (P-chiral) as-P bidentate ligand via an organopalladium complex promoted asymmetric diels-alder reaction between Ph2AsCH=CH2 and 1-phenyl-3,4-dimethylphosphole|
|Source:||Aw, B.-H.,Leung, P.-H.,White, A.J.P.,Williams, D.J. (1996-08-20). Asymmetric synthesis of a (P-chiral) as-P bidentate ligand via an organopalladium complex promoted asymmetric diels-alder reaction between Ph2AsCH=CH2 and 1-phenyl-3,4-dimethylphosphole. Organometallics 15 (17) : 3640-3643. ScholarBank@NUS Repository.|
|Abstract:||Convenient access to the enantiomerically pure rigid bidentate ligand (-)-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7(S)phosphabicyclo[2.2.1]hept-2- ene is established via an asymmetric [4 + 2] cycloaddition between diphenylvinylarsine and 1-phenyl-3,4-dimethylphosphole using the chiral organopalladium(II) complex containing ortho-metalated dimethyl[1-(2-naphthyl)ethyl]amine as the reaction promoter. The absolute configurations of the four newly generated stereocenters have been assigned by single-crystal X-ray analysis.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 12, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.