Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/93149
Title: Asymmetric synthesis of a (P-chiral) as-P bidentate ligand via an organopalladium complex promoted asymmetric diels-alder reaction between Ph2AsCH=CH2 and 1-phenyl-3,4-dimethylphosphole
Authors: Aw, B.-H.
Leung, P.-H. 
White, A.J.P.
Williams, D.J.
Issue Date: 20-Aug-1996
Source: Aw, B.-H.,Leung, P.-H.,White, A.J.P.,Williams, D.J. (1996-08-20). Asymmetric synthesis of a (P-chiral) as-P bidentate ligand via an organopalladium complex promoted asymmetric diels-alder reaction between Ph2AsCH=CH2 and 1-phenyl-3,4-dimethylphosphole. Organometallics 15 (17) : 3640-3643. ScholarBank@NUS Repository.
Abstract: Convenient access to the enantiomerically pure rigid bidentate ligand (-)-[5-(diphenylarsino)-2,3-dimethyl-7-phenyl-7(S)phosphabicyclo[2.2.1]hept-2- ene is established via an asymmetric [4 + 2] cycloaddition between diphenylvinylarsine and 1-phenyl-3,4-dimethylphosphole using the chiral organopalladium(II) complex containing ortho-metalated dimethyl[1-(2-naphthyl)ethyl]amine as the reaction promoter. The absolute configurations of the four newly generated stereocenters have been assigned by single-crystal X-ray analysis.
Source Title: Organometallics
URI: http://scholarbank.nus.edu.sg/handle/10635/93149
ISSN: 02767333
Appears in Collections:Staff Publications

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