Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.200600376
Title: Anisotropic movements of coordination polymers upon desolvation: Solid-state transformation of a linear 1D coordination polymer to a ladderlike structure
Authors: Nagarathinam, M. 
Vittal, J.J. 
Keywords: Crystal engineering
Ladder polymers
Silver
Solid-state reactions
Stacking interactions
Issue Date: 26-Jun-2006
Source: Nagarathinam, M., Vittal, J.J. (2006-06-26). Anisotropic movements of coordination polymers upon desolvation: Solid-state transformation of a linear 1D coordination polymer to a ladderlike structure. Angewandte Chemie - International Edition 45 (26) : 4337-4341. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200600376
Abstract: (Chemical Equation Presented) Rungs of a ladder: A solvated linear 1D coordination polymer [Ag(μ-bpe) (H2O)]-(CF3CO 2)·CH3CN (bpe = 4,4′-bipyridyl-ethylene) with no parallel dispositions of the double bonds in the crystal structure undergoes photodimerization when desolvated. This finding is attributed to the lateral movements of adjacent linear strands on desolvation, which form a ladderlike structure (see picture; Ag light blue, C gray, N purple, O red). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/93106
ISSN: 14337851
DOI: 10.1002/anie.200600376
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