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|Title:||An infrared and electronic spectroscopic study of a series of nickel(II) amine complexes|
Nickel(II) amine complexes
|Citation:||Roe, S.P., Hill, J.O., Magee, R.J. (1991-06). An infrared and electronic spectroscopic study of a series of nickel(II) amine complexes. Monatshefte für Chemie Chemical Monthly 122 (6-7) : 467-478. ScholarBank@NUS Repository. https://doi.org/10.1007/BF00809798|
|Abstract:||Qualitative infrared and electronic spectroscopic data for a series of nickel(II) amine complexes suggest structures involving octahedral (transtetragonal) symmetry and associated with varying degrees of cation-anion interaction. N-methyl ligand substituents contribute significantly to ligand conformations, complex symmetry, and cation-anion steric interactions. From the electronic data, the parameters Dq, B′, C, C/B′, β35, and Z* are determined for each complex and a spectrochemical and nephelauxetic series is proposed for the associated amine ligands. © 1991 Springer-Verlag.|
|Source Title:||Monatshefte für Chemie Chemical Monthly|
|Appears in Collections:||Staff Publications|
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