Please use this identifier to cite or link to this item:
|Title:||(Cyclopentadienyl)chromiumtricarbonyl dimers as a source of metal-centered free-radicals to form stable η2-bonded spin-adducts with fullerenes|
Fullerenes C60, C70
Metal-centered free radicals
|Citation:||Sokolov, V.I., Gasanov, R.G., Goh, L.Y., Weng, Z., Chistyakov, A.L., Stankevich, I.V. (2005-04-29). (Cyclopentadienyl)chromiumtricarbonyl dimers as a source of metal-centered free-radicals to form stable η2-bonded spin-adducts with fullerenes. Journal of Organometallic Chemistry 690 (9) : 2370-2375. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.03.002|
|Abstract:||Spin-adducts (I, IIb-c) of C60 and C70 with metal-centered free radicals CpCr(CO)3 (I, IIa) have been generated in toluene via interaction between fullerenes and the weakly metal-metal bonded dimeric complexes [CpCr(CO)3]2 (Cp = η5- C5H5 (I); Cp = η5-C5Me 5 (II)). Their structures have been investigated using ESR spectroscopy and DFT-PBE calculations and η2-bonding to the CC bond between two hexagons in C60 has been established. Calculations have been extended to investigate the nature of the intermediate η2-coordinated toluene chromium complexes (I, IId). © 2005 Elsevier B.V. All rights reserved.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 12, 2019
WEB OF SCIENCETM
checked on Jan 2, 2019
checked on Dec 28, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.