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|Title:||Spectral reconstruction of in situ FTIR spectroscopic reaction data using band-target entropy minimization (BTEM): Application to the homogeneous rhodium catalyzed hydroformylation of 3,3-dimethylbut-1-ene using Rh 4(CO)12|
In situ FTIR
|Citation:||Li, C., Widjaja, E., Garland, M. (2003-01-25). Spectral reconstruction of in situ FTIR spectroscopic reaction data using band-target entropy minimization (BTEM): Application to the homogeneous rhodium catalyzed hydroformylation of 3,3-dimethylbut-1-ene using Rh 4(CO)12. Journal of Catalysis 213 (2) : 126-134. ScholarBank@NUS Repository. https://doi.org/10.1016/S0021-9517(02)00009-X|
|Abstract:||The homogeneous catalytic hydroformylation of 3,3-dimethylbut-1-ene was studied, starting with Rh4(σ-CO)9(μ-CO) 3 as catalyst. The multiple experiment in situ spectroscopic data were preconditioned to subtract the absorbance due to background moisture, carbon dioxide, and solvent. The preconditioned data were then subjected to band-target entropy minimization (BTEM) in order to recover the pure component spectra of the species present - using no libraries and no a priori information. The pure component spectra of the main species present, namely, the organic reactant 3,3-dimethylbut-1-ene, the organic product 4,4-dimethylpentanal, the catalyst precursor Rh4(σ-CO)9(μ-CO)3, and the observable organometallic intermediate RCORh(CO)4, were all readily recovered. In addition, it was possible to recover the expected minor species, namely 2-methyl-3,3-dimethylbutanal, Rh6(CO)16, and a recently identified cluster Rh4(σ-CO)12. The latter two species exist at ppm levels. The new BTEM algorithm shows that successful and detailed in situ spectroscopic system identification for catalytic studies is possible given no prior information. © 2002 Elsevier Science (USA). All rights reserved.|
|Source Title:||Journal of Catalysis|
|Appears in Collections:||Staff Publications|
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