Please use this identifier to cite or link to this item:
|Title:||Pathways for the hydrolysis of phorate: Product studies by 31P NMR and GC-MS|
Intramolecular nucleophilic attack
|Source:||Hong, F., Pehkonen, S.O., Brooks, E. (2000-07). Pathways for the hydrolysis of phorate: Product studies by 31P NMR and GC-MS. Journal of Agricultural and Food Chemistry 48 (7) : 3013-3017. ScholarBank@NUS Repository. https://doi.org/10.1021/jf990558u|
|Abstract:||A new intramolecular mechanism is proposed for the hydrolysis of phorate. 31P NMR was used to study the formation of P-containing products of phorate hydrolysis in situ. When hydrolysis was followed by 31P NMR, a dominant P-containing product was found and was identified to be diethyl dithiophosphate using methylation and GC-MS. Combining the data from phorate hydrolysis at three different temperatures, thermodynamic parameters were calculated. The contributions of various possible pathways to phorate hydrolysis are discussed.|
|Source Title:||Journal of Agricultural and Food Chemistry|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 16, 2018
WEB OF SCIENCETM
checked on Dec 11, 2017
checked on Jan 13, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.