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Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/91951
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dc.titleElectrochemical and optical characteristics of the hole conducting material N,N′-diphenylbenzidine during oxidation in DMF
dc.contributor.authorNiu, J.
dc.contributor.authorLee, J.Y.
dc.contributor.authorNeudeck, A.
dc.contributor.authorDunsch, L.
dc.date.accessioned2014-10-09T09:53:00Z
dc.date.available2014-10-09T09:53:00Z
dc.date.issued1999-02-12
dc.identifier.citationNiu, J.,Lee, J.Y.,Neudeck, A.,Dunsch, L. (1999-02-12). Electrochemical and optical characteristics of the hole conducting material N,N′-diphenylbenzidine during oxidation in DMF. Synthetic Metals 99 (2) : 133-142. ScholarBank@NUS Repository.
dc.identifier.issn03796779
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/91951
dc.description.abstractThe electrochemical oxidation of the hole conducting material N,N′-diphenylbenzidine (DPB) in N,N-dimethylformamide (DMF) was investigated by cyclic voltammetry and spectroelectrochemistry. The results were compared to electro-oxidation in acetonitrile. Time-resolved UV-Vis spectroscopy, with spectra measured on a time scale of 20 ms by a diode array spectrometer, was used in conjunction with cyclic voltammetry to monitor the progress of electrochemical oxidation and reduction in situ and to obtain kinetic and structural information on reaction products. The oxidation of DPB in DMF is quasi-reversible at Esw
dc.sourceScopus
dc.subjectAromatic amines
dc.subjectCyclic voltammetry
dc.subjectDiphenylbenzidine
dc.subjectLight-emitting diode components
dc.subjectOxidation mechanism
dc.subjectSpectroelectrochemistry
dc.typeArticle
dc.contributor.departmentCHEMICAL & ENVIRONMENTAL ENGINEERING
dc.description.sourcetitleSynthetic Metals
dc.description.volume99
dc.description.issue2
dc.description.page133-142
dc.description.codenSYMED
dc.identifier.isiutNOT_IN_WOS
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