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|Title:||Band-target entropy minimization (BTEM): An advanced method for recovering unknown pure component spectra. Application to the FTIR spectra of unstable organometallic mixtures|
|Source:||Chew, W., Widjaja, E., Garland, M. (2002-04-29). Band-target entropy minimization (BTEM): An advanced method for recovering unknown pure component spectra. Application to the FTIR spectra of unstable organometallic mixtures. Organometallics 21 (9) : 1982-1990. ScholarBank@NUS Repository. https://doi.org/10.1021/om0108752|
|Abstract:||A band-target entropy minimization (BTEM) algorithm tested on experimental FTIR data of Rh4(CO)12/Rh6(CO)16 mixtures to recover the pure component spectra of the constituent complexes was discussed. The targeted band was retained and exceptionally accurate whole spectral estimates of Rh4(CO)12 and Rh6(CO)16 were found to be obtained. The comparison of BTEM algorithm to other algorithms which includes SIMPLISMA, IPCA and OPA-ALS was also presented.|
|Appears in Collections:||Staff Publications|
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