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|Title:||XPS studies of some chemically-synthesized polypyridazine-acceptor complexes|
|Authors:||Kang, E.T. |
|Keywords:||charge transfer complexes|
|Citation:||Kang, E.T.,Neoh, K.G.,Tan, K.L.,Tan, B.T.G. (1989-07). XPS studies of some chemically-synthesized polypyridazine-acceptor complexes. Synthetic Metals 31 (1) : 79-94. ScholarBank@NUS Repository.|
|Abstract:||X-ray photoelectron spectroscopy (XPS) studies are performed on semiconductive polypyridazine (PPd)-I2, PPd-2,3-dichloro-5,6,-dicyano-p-benzoquinone (DDQ), PPd-7,7,8,8-tetracyano-p-quinodimethane (TCNQ) and various PPd-halobenzoquinone complexes, prepared via the simultaneous chemical polymerization and oxidation of pyridazine by the respective acceptor. In all complexes, the XPS data suggest the presence of positively-charged pyridazinium nitrogen. For complexes involving organic acceptors, the negative charges are localized onto the function groups of the acceptors, with the charge transfer (CT) interactions proceeding further than the formation of pure molecular complex. © 1989.|
|Source Title:||Synthetic Metals|
|Appears in Collections:||Staff Publications|
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