Optical non-linearity of distorted cubic cage-shaped cluster compounds {MAg3S3[S2P(OCH2CH3) 2]}(S)(Ph3P)3 (M = W, Mo)

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0277-5387(96)00345-2

Title:	Optical non-linearity of distorted cubic cage-shaped cluster compounds {MAg3S3[S2P(OCH2CH3) 2]}(S)(Ph3P)3 (M = W, Mo)
Authors:	Wu, X. Wang, Q. Shi, S.
Keywords:	Cluster compound Incomplete cubane-like Molybdenum Optical non-linearity Silver Tungsten
Issue Date:	17-Dec-1996
Citation:	Wu, X., Wang, Q., Shi, S. (1996-12-17). Optical non-linearity of distorted cubic cage-shaped cluster compounds {MAg3S3[S2P(OCH2CH3) 2]}(S)(Ph3P)3 (M = W, Mo). Polyhedron 16 (6) : 945-948. ScholarBank@NUS Repository. https://doi.org/10.1016/S0277-5387(96)00345-2
Abstract:	The non-linear optical (NLO) properties of two distorted cage clusters {WAg3S3 [S2P(OCH2 CH3)2]}(S)(Ph3P)3 (1) and {MoAg3S3[S2P(OCH2CH 3)2]}(S)(Ph3P)3 (2) were studied. Both NLO absorption and refraction were observed with 1 and 2, third-order effects were detected with α2 = 6 × 10-10 mW-1 for 1 and α2 = 8 × 10-10 mW-1 for 2. NLO refraction was also found on 1 and 2, with n2 = 1 × 10-16 m2 W-1 for 2. The non-linearity of these two clusters was compared with some related NLO materials. Copyright © 1996 Elsevier Science Ltd.
Source Title:	Polyhedron
URI:	http://scholarbank.nus.edu.sg/handle/10635/91611
ISSN:	02775387
DOI:	10.1016/S0277-5387(96)00345-2
Appears in Collections:	Staff Publications

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