Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/91414
Title: Charge transfer interactions and redox states in poly(N-methylaniline) and its complexes
Authors: Kang, E.T. 
Neoh, K.G. 
Tan, K.L. 
Wong, H.K.
Keywords: doping
oxidation states
poly(N-methylaniline)
protonation
XPS
Issue Date: 1-Jul-1992
Source: Kang, E.T.,Neoh, K.G.,Tan, K.L.,Wong, H.K. (1992-07-01). Charge transfer interactions and redox states in poly(N-methylaniline) and its complexes. Synthetic Metals 48 (2) : 231-240. ScholarBank@NUS Repository.
Abstract: Poly(N-methylaniline) (PMAN) complexes have been synthesized by oxidative polymerization of N-methylaniline in a 1 M HCl solution of (NH4)2S2O8 and in acetonitrile solution of Fe(ClO4)3·9H2O. The PMAN base is susceptible to (i) protonation by protonic acids, (ii) oxidation by inorganic and organic oxidants and (iii) self-doping upon sulfonation. The structures, chemical compositions and doping/protonation levels of the various complexes have been studied by X-ray photoelectron spectroscopy (XPS). The XPS results suggest that PMAN is capable of assuming a 50% oxidized structure, instead of the deprotonated 14% oxidized structure reported earlier. © 1992.
Source Title: Synthetic Metals
URI: http://scholarbank.nus.edu.sg/handle/10635/91414
ISSN: 03796779
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

37
checked on Feb 17, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.