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|Title:||Well-defined polymer-germanium hybrids via surface-initiated atom transfer radical polymerization on hydrogen-terminated Ge(100) substrates|
|Authors:||Xu, F.J. |
|Citation:||Xu, F.J., Cai, Q.J., Kang, E.T., Neoh, K.G., Zhu, C.X. (2005-03-28). Well-defined polymer-germanium hybrids via surface-initiated atom transfer radical polymerization on hydrogen-terminated Ge(100) substrates. Organometallics 24 (7) : 1768-1771. ScholarBank@NUS Repository. https://doi.org/10.1021/om049095u|
|Abstract:||UV-induced hydrogermylation of 4-vinylbenzyl chloride (VBC) on the hydrogen-terminated Ge(100) (Ge-H) surface provided a stable Ge-C bonded initiator monolayer (the Ge-VBC surface) for the surface-initiated atom transfer radical polymerization (ATRP). Well-defined polymer-Ge hybrids, consisting of covalently tethered functional polymer brushes, were prepared via surface-initiated ATRP from the Ge-VBC surfaces. Surface-initiated block copolymerization studies revealed that the chain growth from the functionalized germanium surface was a controlled process. © 2005 American Chemical Society.|
|Appears in Collections:||Staff Publications|
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