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|Title:||Two-phase synthesis of small thiolate-protected Au15 and Au 18 nanoclusters|
|Citation:||Yao, Q., Yu, Y., Yuan, X., Yu, Y., Xie, J., Lee, J.Y. (2013-08-26). Two-phase synthesis of small thiolate-protected Au15 and Au 18 nanoclusters. Small 9 (16) : 2696-2701. ScholarBank@NUS Repository. https://doi.org/10.1002/smll.201203112|
|Abstract:||A one-pot two-phase method for the direct synthesis of small Au (Au 15 and Au18) nanoclusters (NCs) of high purity is developed. A mild reductant is combined with two equilibria (i.e., equilibrium partition and aggregation-dissociation equilibrium) to provide a constant reaction environment for the formation of monodisperse small Au NCs. The pH sensitivity of the aggregation-dissociation equilibrium is used to tailor the cluster size. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.|
|Appears in Collections:||Staff Publications|
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