The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems

Abstract

A non-ideal system containing several solutes, e.g. methanol, acetone, and 2-butanol in n-hexane was studied. Traditionally defined excess molar volumes (based on pure component molar volumes) of the multi-component solutions were measured in the limit of infinite dilution in n-hexane using a vibrating-tube densitometer at 298.15K and 1.0125×105Pa. An experimental design in the concentration range 0.0015