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https://doi.org/10.1016/j.ces.2004.12.044
Title: | The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems |
Authors: | Tjahjono, M. Guo, L. Garland, M. |
Keywords: | Experimental design Inverse problems Numerical analysis Parameter identification Solutions Thermodynamic process |
Issue Date: | Jun-2005 |
Source: | Tjahjono, M., Guo, L., Garland, M. (2005-06). The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems. Chemical Engineering Science 60 (12) : 3239-3249. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ces.2004.12.044 |
Abstract: | A non-ideal system containing several solutes, e.g. methanol, acetone, and 2-butanol in n-hexane was studied. Traditionally defined excess molar volumes (based on pure component molar volumes) of the multi-component solutions were measured in the limit of infinite dilution in n-hexane using a vibrating-tube densitometer at 298.15K and 1.0125×105Pa. An experimental design in the concentration range 0.0015 |
Source Title: | Chemical Engineering Science |
URI: | http://scholarbank.nus.edu.sg/handle/10635/90316 |
ISSN: | 00092509 |
DOI: | 10.1016/j.ces.2004.12.044 |
Appears in Collections: | Staff Publications |
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