Please use this identifier to cite or link to this item:
|Title:||Modified ligand-exchange for efficient solubilization of CdSe/ZnS quantum dots in water: A procedure guided by computational studies|
|Citation:||Pong, B.-K., Trout, B.L., Lee, J.-Y. (2008-05-20). Modified ligand-exchange for efficient solubilization of CdSe/ZnS quantum dots in water: A procedure guided by computational studies. Langmuir 24 (10) : 5270-5276. ScholarBank@NUS Repository. https://doi.org/10.1021/la703431j|
|Abstract:||One of the methods to render CdSe/ZnS core-shell quantum dots(QDots) water-soluble is to functionalize the surface with carboxylate groups by the use of heterobifunctional ligands such as 3-mercaptopropionic acid, where the thiolic end binds onto the outer ZnS shell. However, currently available ligand-exchange procedures starting with TOPO-capped quantum dots often lead to significant loss of quantum yields and poor stability of the colloids in water. As part of our efforts to overcome these problems, we used computational methods to understand the nature of binding between alkyl thiols and ZnS wurtzite surfaces. Guided by the computational results, we modified the ligand-exchange method and increased the reactivity of 3-mercaptopropionic acid toward the ZnS surface in chloroform. The functionlization reaction required only mild reaction conditions and led to QDot nanoparticles that were individually dispersed in water with good colloidal stability. Importantly, the photoluminescence performance of the QDots was highly preserved. © 2008 American Chemical Society.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 17, 2019
WEB OF SCIENCETM
checked on Jan 9, 2019
checked on Jan 12, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.