Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.chemosphere.2005.03.095
Title: Kinetic assessment of the potassium ferrate(VI) oxidation of antibacterial drug sulfamethoxazole
Authors: Sharma, V.K.
Mishra, S.K.
Ray, A.K. 
Keywords: Kinetics
Oxidation
Potassium ferrate(VI)
Sulfamethoxazole
Water treatment
Issue Date: Jan-2006
Citation: Sharma, V.K., Mishra, S.K., Ray, A.K. (2006-01). Kinetic assessment of the potassium ferrate(VI) oxidation of antibacterial drug sulfamethoxazole. Chemosphere 62 (1) : 128-134. ScholarBank@NUS Repository. https://doi.org/10.1016/j.chemosphere.2005.03.095
Abstract: Sulfamethoxazole (SMX), a worldwide-applied antibacterial drug, was recently found in surface waters and in secondary wastewater effluents, which may result in ecotoxical effects in the environment. Herein, removal of SMX by environmentally-friendly oxidant, potassium ferrate(VI) (K2FeO 4), is sought by studying the kinetics of the reaction between Fe(VI) and SMX as a function of pH (6.93-9.50) and temperature (15-45°C). The rate law for the oxidation of SMX by Fe(VI) is first-order with respect to each reactant. The observed second-order rate constant decreased non-linearly from 1.33 ± 0.08 × 103 M-1 s-1 to 1.33 ± 0.10 × 100 M-1 s-1 with an increase of pH from 7.00 to 9.50. This is related to protonation of Fe(VI) (HFeO4-⇔H++FeO42-; pKa,HFeO4 = 7.23) and sulfamethoxazole (SH ⇔ H+ + S-; pKa,SH = 5.7). The estimated rate constants were k11 (HFeO4-+SH)=3.0×104 M-1 s-1, k12 (HFeO4-+S-)=1.7×102 M-1 s -1, and k13 (FeO42-+SH)=1.2×100 M-1 s-1. The energy of activation at pH 7.0 was found to be 1.86 ± 0.04 kJ mol-1. If excess potassium ferrate(VI) concentration (10 μM) is used than the SMX in water, the half-life of the reaction using a rate constant obtained in our study would be approximately 2 min at pH 7. The reaction rates are pH dependent; thus, so are the half-lives of the reactions. The results suggest that K2FeO4 has the potential to serve as an oxidative treatment chemical for removing SMX in water.
Source Title: Chemosphere
URI: http://scholarbank.nus.edu.sg/handle/10635/89304
ISSN: 00456535
DOI: 10.1016/j.chemosphere.2005.03.095
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

70
checked on Oct 17, 2018

WEB OF SCIENCETM
Citations

63
checked on Oct 9, 2018

Page view(s)

58
checked on Sep 21, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.