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|Title:||Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes|
|Authors:||Yen, S.K. |
Andy Hor, T.S.
|Citation:||Yen, S.K., Koh, L.L., Huynh, H.V., Andy Hor, T.S. (2009-02-01). Formation and structures of Pd(II) N,S-heterocyclic carbene-pyridyl mixed-ligand complexes. Journal of Organometallic Chemistry 694 (3) : 332-338. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.10.048|
|Abstract:||Mononuclear mixed-ligand complexes of Pd(II) containing a N,S-heterocyclic carbene (NSHC) with a secondary alkyl N-substituent and pyridyl ligand, with the general formula [PdI2(C10H11NS)L] (C10H11NS = 3-isopropylbenzothiazolin-2-ylidene; L = pyridine, 2-aminopyridine, 3-iodopyridine and 4-tert-butyl-pyridine) have been synthesized and characterized by X-ray single-crystal crystallography. Both solution and solid-state structures, as evident from their 1H NMR spectra and X-ray structures, show anagostic γ-hydrogen interactions of metal with methine of the substituent on the carbene or pyridyl ligand giving 5-membered-chelate-like structures. © 2008.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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