Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.cattod.2007.10.090
DC Field | Value | |
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dc.title | Dendritic SBA-15 supported Wilkinson's catalyst for hydroformylation of styrene | |
dc.contributor.author | Li, P. | |
dc.contributor.author | Kawi, S. | |
dc.date.accessioned | 2014-10-09T06:45:46Z | |
dc.date.available | 2014-10-09T06:45:46Z | |
dc.date.issued | 2008-02-29 | |
dc.identifier.citation | Li, P., Kawi, S. (2008-02-29). Dendritic SBA-15 supported Wilkinson's catalyst for hydroformylation of styrene. Catalysis Today 131 (1-4) : 61-69. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cattod.2007.10.090 | |
dc.identifier.issn | 09205861 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/88739 | |
dc.description.abstract | After PAMAM (polyamidoamine) dendrimers have been successfully grown in SBA-15 mesoporous materials, Wilkinson's catalyst (RhCl(PPh3)3) precursor has been tethered on these dendritic supports to produce heterogeneous catalysts for hydroformylation reaction of styrene. SBA-15 has been functionalized by two methods. In the passivation method, the silanols outside the SBA-15 pores have been passivated to preclude the rhodium precursor to be tethered outside the channels. The rhodium catalysts supported in the pore channels of this passivated SBA-15 show positive dendritic effects in enhancing the catalytic activity, regio-selectivity and stability of the catalyst by minimizing the leaching of the rhodium complex catalyst from the catalyst support to the liquid-phase media. © 2007. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.cattod.2007.10.090 | |
dc.source | Scopus | |
dc.subject | Hydroformylation | |
dc.subject | Passivation | |
dc.subject | SBA-15 | |
dc.subject | Styrene | |
dc.subject | Wilkinson's catalyst | |
dc.type | Article | |
dc.contributor.department | CHEMICAL & BIOMOLECULAR ENGINEERING | |
dc.description.doi | 10.1016/j.cattod.2007.10.090 | |
dc.description.sourcetitle | Catalysis Today | |
dc.description.volume | 131 | |
dc.description.issue | 1-4 | |
dc.description.page | 61-69 | |
dc.description.coden | CATTE | |
dc.identifier.isiut | 000253382100009 | |
Appears in Collections: | Staff Publications |
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