Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jcis.2009.06.021
Title: Preparation and characterization of zirconium-based magnetic sorbent for arsenate removal
Authors: Zheng, Y.-M. 
Lim, S.-F.
Chen, J.P. 
Keywords: Adsorption
Arsenate
Iron
Magnetic sorbent
Spectroscopic analysis
Zirconium
Issue Date: 1-Oct-2009
Citation: Zheng, Y.-M., Lim, S.-F., Chen, J.P. (2009-10-01). Preparation and characterization of zirconium-based magnetic sorbent for arsenate removal. Journal of Colloid and Interface Science 338 (1) : 22-29. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jcis.2009.06.021
Abstract: In this study, a zirconium-based magnetic sorbent is developed by a coprecipitation technology. The characterization of the sorbent and its adsorption behavior are systematically investigated. It is shown that the sorbent has a small mean diameter of 543.7 nm, a specific surface area of 151 m2/g, and a pHzpc of 7. The sorbent has a rough surface and many pores developed on the surface. It has a molecular formula of ZrO(OH)2·1.6Fe3O4·2.5H2O, which was determined by the thermal gravimetric analysis, the elemental analysis, and the digestion experiments. The sorption equilibrium can be reached within 25 h. Better adsorption can be obtained at lower pH, and the optimal initial pH is from 2.6 to 3.3. The maximum adsorption capacity of 45.6 mg-As/g is achieved, which is much higher than many reported sorbents. FTIR spectra analysis indicates that -OH groups play an important role in the uptake. Some of the arsenate are reduced to arsenite after its adsorption onto the magnetic sorbent; the divalent iron in the sorbent may provide electrons for the reduction. A conceptual model for the adsorption of arsenate by the magnetic sorbent is proposed to illustrate the mechanism. © 2009 Elsevier Inc. All rights reserved.
Source Title: Journal of Colloid and Interface Science
URI: http://scholarbank.nus.edu.sg/handle/10635/87598
ISSN: 00219797
DOI: 10.1016/j.jcis.2009.06.021
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