Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.chroma.2010.08.012
Title: Determination of aldehydes in rainwater using micro-solid-phase extraction and high-performance liquid chromatography
Authors: Basheer, C.
Pavagadhi, S.
Yu, H.
Balasubramanian, R. 
Lee, H.K. 
Keywords: Carbonyls
Derivatization
Microextraction
Rainwater
Issue Date: Oct-2010
Citation: Basheer, C., Pavagadhi, S., Yu, H., Balasubramanian, R., Lee, H.K. (2010-10). Determination of aldehydes in rainwater using micro-solid-phase extraction and high-performance liquid chromatography. Journal of Chromatography A 1217 (41) : 6366-6372. ScholarBank@NUS Repository. https://doi.org/10.1016/j.chroma.2010.08.012
Abstract: A simple and rapid extraction procedure was developed for determining aldehydes in rainwater samples. This extraction technique involved the use of micro-solid-phase extraction in which the sorbent was held within a polypropylene membrane envelope, followed by high-performance liquid chromatographic analysis. Aldehydes such as formaldehyde, acetaldehyde, propionaldehyde and valeraldehyde were used as model compounds. Extraction conditions were optimized. The method linearity ranged between 0.5 and 50μgl-1 with the correlation coefficient of 0.987-0.999. The relative standard deviations (RSDs) of the method ranged from 7 to 12%. Method detection limits were in the range of 0.07-0.15μgl-1, which is lower than those previously reported for solid-phase microextraction combined with gas chromatography-mass spectrometric techniques. The proposed extraction technique was used for determination of aldehydes in rainwater samples to demonstrate the applicability of the method. © 2010 Elsevier B.V.
Source Title: Journal of Chromatography A
URI: http://scholarbank.nus.edu.sg/handle/10635/87479
ISSN: 00219673
DOI: 10.1016/j.chroma.2010.08.012
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