Please use this identifier to cite or link to this item:
|Title:||Electronically and ionically conductive gels of ionic liquids and charge-transfer tetrathiafulvalene-tetracyanoquinodimethane|
|Citation:||Mei, X., Ouyang, J. (2011-09-06). Electronically and ionically conductive gels of ionic liquids and charge-transfer tetrathiafulvalene-tetracyanoquinodimethane. Langmuir 27 (17) : 10953-10961. ScholarBank@NUS Repository. https://doi.org/10.1021/la202465k|
|Abstract:||Electronically and ionically conductive gels were fabricated by mixing and mechanically grinding neutral tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ) in ionic liquids (ILs) like 3-ethyl-1- methylimidazolium dicyanoamide (EMIDCA), 1-ethyl-3-methylimidazolium thiocyanate (EMISCN), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMITf 2N), trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl) imide (P 14,6,6,6Tf 2N), and methyl-trioctylammonium bis(trifluoromethylsulfonyl)imide (MOATf 2N). Charge-transfer TTF-TCNQ crystallites were generated during the mechanical grinding as indicated by the UV-visibile-near-infrared (UV-vis-NIR) absorption spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction. The charge-transfer TTF-TCNQ crystallites have a needle-like shape. They form solid networks to gelate the ILs. The gel behavior is confirmed by the dynamic mechanical measurements. It depends on both the anions and cations of the ILs. In addition, when 1-methyl-3-butylimidazolium tetrafluoroborate (BMIBF 4) and 1-methyl-3-propylimidazolium iodide (PMII) were used, the TTF-TCNQ/IL mixtures did not behave as gels. The TTF-TCNQ/IL gels are both electronically and ionically conductive, because the solid phase formed by the charge-transfer TTF-TCNQ crystallites is electronically conductive, while the ILs are ionically conductive. The gel formation is related to needle-like charge-transfer TTF-TCNQ cyrstallites and the π-π and Coulombic interactions between TTF-TCNQ and ILs. © 2011 American Chemical Society.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Sep 25, 2018
WEB OF SCIENCETM
checked on Sep 17, 2018
checked on Sep 14, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.