Please use this identifier to cite or link to this item: https://doi.org/10.1021/la803289p
Title: Theoretical insight of physical adsorption for a single-component adsorbent + adsorbate system: I. thermodynamic property surfaces
Authors: Chakraborty, A. 
Saha, B.B. 
Ng, K.C. 
Koyama, S.
Srinivasan, K.
Issue Date: 17-Feb-2009
Citation: Chakraborty, A., Saha, B.B., Ng, K.C., Koyama, S., Srinivasan, K. (2009-02-17). Theoretical insight of physical adsorption for a single-component adsorbent + adsorbate system: I. thermodynamic property surfaces. Langmuir 25 (4) : 2204-2211. ScholarBank@NUS Repository. https://doi.org/10.1021/la803289p
Abstract: Thermodynamic property surfaces for a single-component adsorbent + adsorbate system are derived and developed from the viewpoint of classical thermodynamics, thermodynamic requirements of chemical equilibrium, Gibbs law, and Maxwell relations. They enable us to compute the entropy and enthalpy of the adsorbed phase, the isosteric heat of adsorption, specific heat capacity, and the adsorbed phase volume thoroughly. These equations are very simple and easy to handle for calculating the energetic performances of any adsorption system. We have shown here that the derived thermodynamic formulations fill up the information gap with respect to the state of adsorbed phase to dispel the confusion as to what is the actual state of the adsorbed phase. We have also discussed and established the temperature-entropy diagrams of (i) CaCl 2-in-silica gel + water system for cooling applications, and (ii) activated carbon (Maxsorb III) + methane system for gas storage. © Copyright 2009 American Chemical Society.
Source Title: Langmuir
URI: http://scholarbank.nus.edu.sg/handle/10635/85788
ISSN: 07437463
DOI: 10.1021/la803289p
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