Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.inoche.2004.01.014
Title: Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water
Authors: Yu, Z.
Wang, X.
Feng, Y. 
Zhong, X. 
Keywords: Crystal structure
Cycloaddition
Tetrazole
Zinc
Issue Date: Apr-2004
Citation: Yu, Z., Wang, X., Feng, Y., Zhong, X. (2004-04). Crystallographic characterization of the intermediate in the synthesis of tetrazole from nitrile and azide in water. Inorganic Chemistry Communications 7 (4) : 492-494. ScholarBank@NUS Repository. https://doi.org/10.1016/j.inoche.2004.01.014
Abstract: The intermediate [Zn(4-PTZ)2(H2O)4] (4-PTZ=5-(4-pyridyl N-oxide)tetrazolate) (1) in the synthesis of 4-H-PTZ (2) from cycloaddition reaction of 4-cyanopyridine N-oxide with NaN3 in water catalyzed by ZnCl2 was structurally characterized. The catalysis role of Zn2+ in the synthesis of tetrazole stems from the formation of tetrazolate zinc complex 1. © 2004 Elsevier B.V. All rights reserved.
Source Title: Inorganic Chemistry Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/84552
ISSN: 13877003
DOI: 10.1016/j.inoche.2004.01.014
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

20
checked on Sep 11, 2018

WEB OF SCIENCETM
Citations

18
checked on Sep 11, 2018

Page view(s)

45
checked on Sep 7, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.