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|Title:||Aqua(nitrilotriacetato)(1,10-phenanthroline)iron(III) monohydrate: A seven-coordinate iron(III) complex|
|Authors:||Feng, Y. |
|Citation:||Feng, Y., Ong, S.-L., Hu, J., Ng, W.-J. (2002-01). Aqua(nitrilotriacetato)(1,10-phenanthroline)iron(III) monohydrate: A seven-coordinate iron(III) complex. Acta Crystallographica Section C: Crystal Structure Communications 58 (1) : m34-m35. ScholarBank@NUS Repository. https://doi.org/10.1107/S0108270101017036|
|Abstract:||Reaction of 1,10-phenanthroline (phen) with iron trichloride in the presence of sodium nitrilotriacetate (NTA) resulted in the formation of red crystals of the title complex, [Fe(C6H6NO6)(C12H8N2 )(H2O)]·H2O. The Fe atom has a distorted capped trigonal prismatic coordination comprised of one tetradentate NTA, one bidentate phen molecule and a water molecule. Intermolecular O-H⋯O hydrogen bonds link the molecules into infinite chains. The chains are crosslinked by hydrogen bonds involving the solvent water molecule, leading to an infinite ladder packing mode.|
|Source Title:||Acta Crystallographica Section C: Crystal Structure Communications|
|Appears in Collections:||Staff Publications|
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