Please use this identifier to cite or link to this item: https://doi.org/10.1039/c3ee40321a
Title: Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale
Authors: Stoerzinger, K.A.
Risch, M.
Suntivich, J.
Lü, W.M.
Zhou, J.
Biegalski, M.D.
Christen, H.M.
Ariando 
Venkatesan, T. 
Yang, S.-H.
Issue Date: Jun-2013
Citation: Stoerzinger, K.A., Risch, M., Suntivich, J., Lü, W.M., Zhou, J., Biegalski, M.D., Christen, H.M., Ariando, Venkatesan, T., Yang, S.-H. (2013-06). Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale. Energy and Environmental Science 6 (6) : 1582-1588. ScholarBank@NUS Repository. https://doi.org/10.1039/c3ee40321a
Abstract: We report that the oxygen reduction reaction (ORR) activities of (001)-oriented manganese perovskite films decrease from 10 to 1 nm by more than an order of magnitude, which can be attributed to the barrier associated with interfacial band bending that impedes electron transfer to the electrolyte, and reduction of Mn3+ due to charge transfer from the Nb:SrTiO 3 substrate. Furthermore, we show by substitution in La 1-x(Ca,Sr)xMnO3 that Mn3+, not Mn4+, is the active valence state for ORR. © 2013 The Royal Society of Chemistry.
Source Title: Energy and Environmental Science
URI: http://scholarbank.nus.edu.sg/handle/10635/82858
ISSN: 17545692
DOI: 10.1039/c3ee40321a
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