Please use this identifier to cite or link to this item:
|Title:||Sulfur-functionalized N-heterocyclic carbene complexes of Pd(II): Syntheses, structures and catalytic activities|
|Citation:||Yuan, D., Huynh, H.V. (2012-03). Sulfur-functionalized N-heterocyclic carbene complexes of Pd(II): Syntheses, structures and catalytic activities. Molecules 17 (3) : 2491-2517. ScholarBank@NUS Repository. https://doi.org/10.3390/molecules17032491|
|Abstract:||N-heterocyclic carbenes (NHCs) can be easily modified by introducing functional groups at the nitrogen atoms, which leads to versatile coordination chemistry as well as diverse catalytic applications of the resulting complexes. This article summarizes our contributions to the field of NHCs bearing different types of sulfur functions, i.e., thioether, sulfoxide, thiophene, and thiolato. The experimental evidence for the truly hemilabile coordination behavior of a Pd(II) thioether-NHC complex has been reported as well. In addition, complexes bearing rigid CSC-pincer ligands have been synthesized and the reasons for pincer versus pseudo-pincer formation investigated. Incorporation of the electron-rich thiolato function resulted in the isolation of structurally diverse complexes. The catalytic activities of selected complexes have been tested in Suzuki-Miyaura, Mizoroki-Heck and hydroamination reactions. © 2012 by the authors.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Aug 16, 2018
WEB OF SCIENCETM
checked on Jul 31, 2018
checked on Aug 17, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.