Please use this identifier to cite or link to this item:
|Title:||Molecular architecture and supramolecular association in the zinc-triad 1,1-dithiolates. Steric control as a design element in crystal engineering?|
|Citation:||Tiekink, E.R.T. (2003-04-16). Molecular architecture and supramolecular association in the zinc-triad 1,1-dithiolates. Steric control as a design element in crystal engineering?. CrystEngComm 5 : 101-113. ScholarBank@NUS Repository. https://doi.org/10.1039/b301318a|
|Abstract:||A survey of the fascinating structural chemistry of the zinc-triad 1,1-dithiolates is presented. A total of twelve distinct structural motifs are delineated ranging from monomeric, dimeric, tetrameric, linear polymeric, layer to 3-dimensional network architectures. Such diversity arises from the prevalent secondary bonding interactions, i.e. A⋯S, operating in the solid state. While the variation in structure suggests that the control of secondary interactions is difficult, a possible design tool for crystal engineering is identified, namely by moderating the steric profile of thiolate-bound organic substituents, at least for the systems described herein. © The Royal Society of Chemistry 2003.|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jun 18, 2018
WEB OF SCIENCETM
checked on Jun 5, 2018
checked on Jun 1, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.