Please use this identifier to cite or link to this item: https://doi.org/10.1055/s-0030-1260607
Title: Catalytic decarboxylative reactions: Biomimetic approaches inspired by polyketide biosynthesis
Authors: Pan, Y.
Tan, C.-H. 
Keywords: asymmetric catalysis
decarboxylative reactions
enantioselectivity
malonic acid half thioester
organocatalytic reactions
Issue Date: 2011
Citation: Pan, Y., Tan, C.-H. (2011). Catalytic decarboxylative reactions: Biomimetic approaches inspired by polyketide biosynthesis. Synthesis (13) : 2044-2053. ScholarBank@NUS Repository. https://doi.org/10.1055/s-0030-1260607
Abstract: This short review summarizes decarboxylative reactions of malonic acid half thio/oxyester mediated by metal complexes and organocatalysts. These biomimetic reactions are inspired by similar reactions catalyzed by polyketide synthase. While they have been known for several decades, this is the first review of these reactions. 1 Introduction 2 Decarboxylative Reactions Catalyzed by Metal Complexes 2.1 Condensation Reaction 2.2 Aldol Reaction 2.3 1,4-Addition 3 Organocatalytic Decarboxylative Reactions 3.1 Condensation Reaction 3.2 Aldol Reaction 3.3 1,4-Addition 3.4 Mannich Reaction 3.5 Amination Reaction 3.6 Protonation 4 Conclusion © Georg Thieme Verlag Stuttgart • New York.
Source Title: Synthesis
URI: http://scholarbank.nus.edu.sg/handle/10635/77583
ISSN: 00397881
DOI: 10.1055/s-0030-1260607
Appears in Collections:Staff Publications

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