Please use this identifier to cite or link to this item: https://doi.org/10.1002/ejic.200300730
Title: Diorganotin salicylaldoximate clusters: Their fascinating chemistry and structures
Authors: Gielen, M.
Biesemans, M.
Willem, R.
Tiekink, E.R.T. 
Keywords: Cluster compounds
NMR spectroscopy
Substitution reactions
Tin
X-ray diffraction
Issue Date: 6-Feb-2004
Citation: Gielen, M., Biesemans, M., Willem, R., Tiekink, E.R.T. (2004-02-06). Diorganotin salicylaldoximate clusters: Their fascinating chemistry and structures. European Journal of Inorganic Chemistry (3) : 445-451. ScholarBank@NUS Repository. https://doi.org/10.1002/ejic.200300730
Abstract: A large variety of small oxotin clusters, characterised as stable crystalline products or solution transients, has been obtained by the reaction of various diorganotin oxides and salicylaldoxime. The structures were investigated by high resolution multinuclear NMR methods and X-ray crystallography. The predominant trinuclear clusters contain one seven- and two five-coordinate tin atoms and undergo a series of reversible substitution reactions, including those leading to clusters of differing nuclearity, in solution at room temperature. Such a variety of structures is rather unusual in organotin chemistry. © Wiley-VCH Verlag GmbH & Co, KGaA, 69451 Weinheim, Germany, 2004.
Source Title: European Journal of Inorganic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/77521
ISSN: 14341948
DOI: 10.1002/ejic.200300730
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

22
checked on Aug 10, 2018

WEB OF SCIENCETM
Citations

20
checked on Jul 11, 2018

Page view(s)

30
checked on Jul 27, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.